Short attosecond (as) or few femtoseconds (fs) IR and UV pulses have a broad energy bandwidth which allows exciting a superposition of several electronic states in neutral molecules and molecular cations.[1] The nature of the states excited can be controlled by tuning the pulse parameters. This opens the way to novel avenues for control by engineering of electronic coherences between selected electronic states to steer charge migration on a purely electronic time scale.[2] As the nuclei begin to move, the electronic and nuclear motions are entangled and the engineered electronic coherences can be usefully exploited for directing the vibronic density through the network of non adiabatic interactions to specific products.
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